| Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O |
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| 引用本文： | Zhi LIU1,Qi FANG1*,Wen Tao YU1,Min Hua JIANG1,De Qing ZHANG 2,Dao Ben ZHU2 1State Key Laboratory of Crystal Materials,Shandong University,Jinan 250100 2Institute of Chemistry,The Chinese Academy of Sciences,Beijing 100080. Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O[J]. 中国化学快报, 2003, 14(4) |
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| 作者姓名： | Zhi LIU1 Qi FANG1* Wen Tao YU1 Min Hua JIANG1 De Qing ZHANG 2 Dao Ben ZHU2 1State Key Laboratory of Crystal Materials Shandong University Jinan 250100 2Institute of Chemistry The Chinese Academy of Sciences Beijing 100080 |
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| 作者单位： | Zhi LIU1，Qi FANG1*，Wen Tao YU1，Min Hua JIANG1，De Qing ZHANG 2，Dao Ben ZHU2 1State Key Laboratory of Crystal Materials，Shandong University，Jinan 250100 2Institute of Chemistry，The Chinese Academy of Sciences，Beijing 100080 |
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| 基金项目： | This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034)，and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy o |
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| 摘 要： | ET is one of the most famous electron-donor molecules, which forms charge-transfer complexes (abbr. CT-complexes) with various types of counterions. These complexes have received intense attention because a wide range of physical properties such as conductivity and superconductivity1, ferromagnetism2-4 and nonlinear optical properties5 was found in these materials. Although the majority of the ET-based CT-complexes were prepared by combining with inorganic counterions, CT-complexes with o…
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Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)2(CH2=CH-CH2-SO3)·H2O |
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| Zhi LIU,Qi FANG,Wen Tao YU,Min Hua JIANG,De Qing ZHANG,Dao Ben ZHU. Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)2(CH2=CH-CH2-SO3)·H2O[J]. Chinese Chemical Letters, 2003, 14(4) |
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| Authors: | Zhi LIU Qi FANG Wen Tao YU Min Hua JIANG De Qing ZHANG Dao Ben ZHU |
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| Abstract: | Electro-oxidation of 3,4,3′, 4(-bis(ethylenedithio)-2,2′,5,5(-tetrathiafulvalen (abbr. ET) in the presence of allylsulfonate affords a new charge-transfer salt (ET)2(CH2=CH-CH2-SO3)×H2O. The single crystal structure of the title compound is determined to be in orthorhombic crystal system, Pma2 space group. This salt is a semiconductor and its room-temperature conductivity is 0.0489Ω-1˙m-1. |
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| Keywords: | ET electro-oxidation crystal structure conductivity. |
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