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Synthesis of VO2 (B) nanorods for Li battery application
Authors:ChV Subba Reddy  Edwin H Walker Jr  SA Wicker Sr  Quinton L Williams  Rajamohan R Kalluru
Institution:aDepartment of Chemistry, Southern University and A&M College, P.O. Box 12566, Baton Rouge, LA 70813, United States;bDepartment of Physics, Atmospheric Sciences and Geoscience, Jackson State University, JSU Box 17660, 1400 J.R. Lynch Street, Jackson, MS 39217, United States
Abstract:Vanadium dioxide nanorods were synthesized through a hydrothermal reaction from V2O5 xerogel, poly(vinyl pyrrolidone) (PVP) and lithium perchlorate (LiClO4). The prepared samples were characterized by X-ray diffraction, infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical discharge–charge cycling in lithium battery. SEM images reveal the nanorods to have dimensions on the order of 1–3 μm in length and 10–50 nm in diameter. The measured initial discharge capacity of the lithium battery with a cathode made of VO2 (B) nanorods was 152 mA h/g.
Keywords:Vanadium oxide xerogel  VO2 nanorods  Lithium battery
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