Reactivity of [Mo(NHNRPh)(NNRPh)(acac)X2] (R=Ph,Me; X=Br,I) toward tertiary phosphines |
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| Abstract: | The reactivity of mixed organohydrazido(1-)]organohydrazido(2-)]molybdenum(VI) complexes Mo(NHNRPh)(NNRPh)(acac)X2] {R?=?Ph, X?=?Br (1); R?=?Ph, X?=?I (2) and R?=?Me; X?=?I (3)} with tertiary phosphines as PPh3, PMePh2 and PMe2Ph are examined. The syntheses of Mo(NNPh2)2Br2(PPh3)] (4), Mo(NNPh2)2Br2(PMePh2)2] (5), Mo(NNPh2)2Br2(PMe2Ph)2] (6), Mo(NNPh2)2(acac)I(PPh3)] (7), Mo(NNPh2)2(acac)(PMePh2)2]+I? (8) and Mo(NNMePh)2(acac)(PMePh2)2]+I? (9) are reported. All complexes were characterized by elemental analysis, UV-visible, IR, 1H and 31P{H} NMR spectroscopy. |
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| Keywords: | Molybdenum complexes Phosphine derivatives Hydrazido(2-) complexes |
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