Copper(I) and Silver(I) Complexes of 1-alkyl-2-(methyl)-4-(arylazo)imidazole. Synthesis, Spectral Studies and Electrochemistry |
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Authors: | Sanjay Senapoti Kamal Krishna Sarker Tapan Kumar Mondal Chittaranjan Sinha |
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Institution: | (1) Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata, 700 032, India |
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Abstract: | 2-(Methyl)-4-(arylazo)imidazole (RLH) (1, 2) are new series of azoimidazoles. Upon treatment of alkylhalide in dry THF in presence of NaH has synthesised 1-alkyl-2-(methyl)-4-(arylazo)imidazole
(RLR′) (3, 4). They belong to the azoimine family of N,N′-chelating ligand. They stabilize the Cu(I) oxidation state and we have synthesized Cu(RLR′)2](ClO4) (5, 6). These complexes show a moderately intense visible band (500–600 nm) which has been assigned to 3d(Cu) → π*(ligand) transition. Ag(I) complexes of RLR′ (7, 8) are also very stable under ambient conditions and show weak transitions in the visible region. The Cu(I)-complexes show high
potential Cu(II)/Cu(I) redox couple > 0.4 V vs Ag, AgCl/Cl− reference electrode. All these complexes have been structurally characterized by 1H NMR spectroscopic data. |
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