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Synthesis of nanoscale antimony particles |
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| Authors: | L. Balan A. Dailly R. Schneider D. Billaud P. Willmann J. Olivier-Fourcade J.-C. Jumas |
| Affiliation: | (1) Laboratoire de Chimie du Solide Minéral (UMR 7555 CNRS), Université Henri Poincaré Nancy I,, BP 239, 54506 Vandoeuvre les Nancy Cedex, France;(2) Laboratoire de Synthèse organométallique et Réactivité (UMR 7565 CNRS), Université Henri Poincaré Nancy I,, BP 239, 54506 Vandoeuvre les Nancy Cedex, France;(3) Centre National d’Etudes Spatiales,, 18 Avenue Edouard Belin, 31401 Toulouse Cedex 9, France;(4) Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (UMR 5072 CNRS),, Université Montpellier, II, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France |
| Abstract: | For the search of new negative electrodes of Li-ion batteries, a low-temperature method has been developed for the preparation of nanoscale antimony particles which uses an alkoxide-activated sodium hydride as reducing agent of antimony pentachloride. X-ray diffraction and TEM studies confirm the obtaining of amorphous Sb nanoparticles dispersed in an organic matrix. 121Sb Mössbauer spectroscopy gives evidence for the occurrence of interactions between antimony and the matrix. These interactions are modified by the washing treatments. |
| Keywords: | nanosized antimony particles amorphous antimony 121Sb M?ssbauer spectroscopy |
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