Spectral Studies on Some Pyrimidine Derivatives in Different Solvents |
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| Authors: | A. A. Hasanein G. M. El-Subruiti G. O. Younes M. H. Srour |
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| Affiliation: | (1) Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 426, Ibrahimia, Alexandria, 21321, Egypt;(2) Department of Chemistry, Faculty of Science, Beirut Arab University, Lebanon |
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| Abstract: | The electronic absorption spectra of 2-aminopyrimidine (compound I), 2-amino-4-methylpyrimidine (compound II), 2-amino-4,6-dimethylpyrimidine (compound III), 2-amino-4,6-dimethoxypyrimidine (compound IV), 4-amino-2,6-dimethylpyrimidine (compound V), and 4,5-diamopyrimidine (compound VI) have been measured in water and in a series of different organic solvents. The solvent effects on the spectra are discussed and the solvent induced spectral shifts are analyzed in terms of different solute–solvent interaction mechanisms, using the multiple linear regression technique. |
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| Keywords: | Electronic spectra spectral shifts organic solvents water pyrimidines |
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