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Sulfur heterocycles. I. Use of 4,4-dimethyl-1,3-oxathiolane-3,3-dioxide as a carbonyl anion equivalent |
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| Authors: | George W. Gokel Harold M. Gerdes David E. Miles John M. Hufnal Glenn A. Zerby |
| Affiliation: | Department of Chemistry The Pennsylvania State University, University Park, Pa 16802 USA;The University of Maryland, College Park, MD 20742 USA |
| Abstract: | The title heterocycle is used as a carbonyl anion equivalent in the preparation of aldehydes and α-silyl ketones; the key step is the thermal demasking of the heterocycle by loss of isobutylene and sulfur dioxide. |
| Keywords: | Address correspondence to this author at Department of Chemistry University of Maryland College Park MD 20742 U.S.A. |
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