The dichlorovinylation of enolates |
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| Authors: | Andrew S. Kende Michel Benechie Dennis P. Curran Pawel Fludzinski Wendy Swenson Jon Clardy |
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| Affiliation: | Department of Chemistry, University of Rochester, Rochester, New York 14627 U.S.A.;Department of Chemistry, Cornell University, Ithaca, New York 14853 U.S.A. |
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| Abstract: | ![]()
The condensation of certain ketone and ester enolates with trichloroethylene proceeds with surprising ease to yield dichlorovinylation products. The stereochemistry for one such product is established by X-ray, and subsequent transformations of these initial products to ethinyl or ω-chloroethinyl derivatives is described. |
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