| Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide |
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| 作者姓名： | Mao Jianmin Hou Zijie Liu Xingping and Li Yulin |
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| 作者单位： | Institute of Organic Chemistry，Lanzhou University，Lanzhou |
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| 基金项目： | Project Supported by National Science Foundation. |
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| 摘 要： | (4R,5S)-2,2-Dimethyl-4-(1',2'-dimethylpropyl)-5-(1'-bromoethyl)--1,3-dioxolane(15) with the side chain of brassinolide and (4R, 5S)--2, 2-dimethyl-4-(l'-methylene-2'-methylpropyl)-5-(1'-bromoethyl) 1,3-dioxolane(14) with the side chain of dolicholide were first synthesized through 11 and 10 stepes from D-mannitol respectively. All of the intermediates 7-13 were first synthesized too.
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Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide |
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| Mao Jianmin,Hou Zijie,Liu Xingping and Li Yulin.Studies on the Syntheses of the Side Chains of Brassinolide and Dolicholide[J].Chemical Research in Chinese University,1988(4). |
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| Authors: | Mao Jianmin Hou Zijie Liu Xingping and Li Yulin |
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| Abstract: | (4R,5S)-2,2-Dimethyl-4-(1',2'-dimethylpropyl)-5-(1'-bromoethyl)--1,3-dioxolane(15) with the side chain of brassinolide and (4R, 5S)--2, 2-dimethyl-4-(l'-methylene-2'-methylpropyl)-5-(1'-bromoethyl) 1,3-dioxolane(14) with the side chain of dolicholide were first synthesized through 11 and 10 stepes from D-mannitol respectively. All of the intermediates 7-13 were first synthesized too. |
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| Keywords: | Brassinolide Dolicholide Side chain |
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