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Evidence for the 1/rij mechanism. Inhomogeneous line broadening in the Rydberg spectrum of naphthalene
Authors:B Sharf
Institution:Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
Abstract:Theoretical discussion of the line shape of vibronic resonances in the Rydberg spectrum of naphthalene is presented. The spectrum provides strong evidence for the 1/rij mechanism recently proposed by the author. The results of this work are in disagreement with the work of Jortner and Morris.
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