Dissociation energy of the NH3 · Hg(P0) complex |
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| Authors: | C.G. FreemanM.J. McEwan R.F.C. ClaridgeL.F. Phillips |
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| Affiliation: | Chemistry Department, University of Canterbury, Christchurch, New Zealand |
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| Abstract: | ![]()
A phase-shift method has been used to study the bimolecular and termolecular reactions of Hg(3P0) with NH3. The bimolecular and termolecular rate constants are 3.8 × 10−13 cm3 molecule−1sec−1 and 1.4 × 10−30 cm6 molecule−2sec−1, respectively. From the difference between the wavelengths of peak emission intensity for the stabilized and unstabilized Hg·NH3 complexes the dissociation energy of the complex is estimated to be 5.0 kcal mole−1. |
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