Effect of the nature of the solvent and the temperature on the frequency and intensity of the stretching vibration of the Ge-H bond in the IR spectra of 1-hydrogermatranes |
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| Authors: | M G Voronkov D S D Toryashinova É I Brodskaya E E Shestakov N Yu Khromova T K Gar |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR;(2) State Scientific-Research Institute of Chemistry and Technology of Heteroorganic Compounds, Moscow |
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| Abstract: | Conclusions The Ge-H stretching vibration in the IR spectra of 1-hydrogermatranes varies under the influence of the solvent and the temperature as a result of the presence of the transannular Ge  N bond. The change in the length of this bond with variation in the polarity of the solvent and the temperature of the solutions is smaller in germatranes than for the Si N bond in the isostructural silatranes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1758–1761, August, 1985. |
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