Experimental investigation and kinetic modeling of the negative temperature coefficient of the reaction rate in rich propane—oxygen mixtures |
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| Authors: | V. I. Vedeneev L. B. Romanovich V. Ya. Basevich V. S. Arutyunov O. V. Sokolov Yu. V. Parfenov |
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| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977 Moscow, Russian Federation |
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| Abstract: | ![]()
The phenomenon of the negative temperature coefficient (NTC) of the reaction rate of the oxidation of rich propane—oxygen mixtures was experimentally studied. The NTC phenomenon is qualitatively described by a simple kinetic model containing a minimum set of reactions related to the oxidation of the starting hydrocarbon, propane, and the propyl C3H7 . radical formed. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2120–2124, December, 1997. |
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| Keywords: | oxidation propane cool flames negative temperature coefficient |
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