| 苝四羧酸二酰亚胺衍生物的合成及其性能研究 |
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| 引用本文： | 徐业伟,朱方华,张海连,张林.苝四羧酸二酰亚胺衍生物的合成及其性能研究[J].合成化学,2009,17(4). |
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| 作者姓名： | 徐业伟 朱方华 张海连 张林 |
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| 作者单位： | 1. 西南科技大学,材料科学与工程学院,四川,绵阳,621002;中国工程物理研究院,激光聚变研究中心,四川,绵阳,621900
2. 中国工程物理研究院,激光聚变研究中心,四川,绵阳,621900 |
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| 基金项目： | 中国工程物理研究院高温高密度等离子体物理国防科技重点实验室资助项目 |
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| 摘 要： | 以苝四羧酸二酐为原料,设计并合成了3个苝四羧酸二酰亚胺类化合物1,7-二溴-3,4,9,10-苝四酸酐(1), N,N′-二(十二烷基)-1,7-二溴-3,4,9,10-苝四羧酸二酰亚胺(2)和N,N′-二(十二烷基)-1,7-二对叔丁基苯氧基-3,4,9,10-苝四羧酸二酰亚胺(3)],其结构经1H NMR和MS表征.用循环伏安法和热分析法研究了2和3的电化学性质和热学性质.结果表明:2和3的氧化电位分别为931.6 mV, 170.1 mV,还原电位分别为-1 028 mV, -1 941 mV;2和3具有高的分解温度(>300 ℃),有良好的热稳定性.
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| 关 键 词： | 苝四羧酸二酰亚胺 合成 循环伏安 热稳定性 |
Synthesis of Perylene Diimide Derivatives and Their Performance Study |
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| XU Ye-wei,ZHU Fang-hua,ZHANG Hai-lian,ZHANG Lin.Synthesis of Perylene Diimide Derivatives and Their Performance Study[J].Chinese Journal of Synthetic Chemistry,2009,17(4). |
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| Authors: | XU Ye-wei ZHU Fang-hua ZHANG Hai-lian ZHANG Lin |
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| Institution: | 1.School of Materials Science and Engineering;Southwest University of Science and Technology;Mianyang 621010;China;2.Research Center of Laser Fusion;China Academy of Engineering Physics;Mianyang 621900;China |
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| Abstract: | Three perylene diimide derivatives1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid bisanhydride(1),N,N'-didodecyl-1,7-dibromoperylene-3,4,9,10-tertracarboxylic acid diimide(2)and N,N'-didodecyl-1,7-di(4-t-butylphenoxy)perylene-3,4,9,10-tertracarboxylic acid diimide(3)] were synthesized from perylene-3,4,9,10-tetracarboxylic acid bisanhydride.The structures were characterized by 1H NMR and MS.The electrochemical and thermal properties of 2 and 3 were investigated by cyclic voltammetry and thermal analysis.... |
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| Keywords: | perylene diimide synthesis cyclic voltammetry thermal stability |
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