| Sn-Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride(or Sodium Borodeuteride) |
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| 引用本文： | 赵刚,胡建兵. Sn-Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride(or Sodium Borodeuteride)[J]. 中国化学, 2003, 0(7) |
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| 作者姓名： | 赵刚 胡建兵 |
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| 作者单位： | State Key Laboratory of Organometallic Chemistry，Laboratory of Modern Synthetic Organic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China，State Key Laboratory of Organometallic Chemistry，Laboratory of Modern Synthetic Organic Chemistry，Shanghai Institute of Organic Chemistry，Chinese Academy of Sciences，Shanghai 200032，China |
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| 基金项目： | Project supported by the Major State Basic Research Development Program(No.G2000048007),the National Natural Science Foundation of China(No.D20032010)and Shanghai Natural Science Council. |
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| 摘 要： | Two remarkable reducing agents NaBH_4 (or NaBD_4)/SnCl_2(orSnCl_4·2Et_2O) with chiral ligands are applied to the asymmetricreduction of carbonyl compounds with excellent chemical yieldsand enantioselective excesses.
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Sn-Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride (or Sodium Borodeuteride) |
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| ZHAO,Gang HU,Jian-BingState Key Laboratory of Organometallic Chemistry,Laboratory of Modern Synthetic Organic Chemistry. Sn-Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride (or Sodium Borodeuteride)[J]. Chinese Journal of Chemistry, 2003, 0(7) |
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| Authors: | ZHAO Gang HU Jian-BingState Key Laboratory of Organometallic Chemistry Laboratory of Modern Synthetic Organic Chemistry |
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| Affiliation: | ZHAO,Gang HU,Jian-BingState Key Laboratory of Organometallic Chemistry,Laboratory of Modern Synthetic Organic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China |
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| Abstract: | |
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| Keywords: | asymmetric reduction chiral ligand carbonyl com-pound |
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