| 配位聚合物[Zn(PDA)(obix)]的合成、晶体结构和荧光性质 |
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| 引用本文： | 朱 坤,许焕民,刘光祥,黄荣谊,任小明.配位聚合物[Zn(PDA)(obix)]的合成、晶体结构和荧光性质[J].无机化学学报,2009,25(9):1677-1681. |
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| 作者姓名： | 朱 坤 许焕民 刘光祥 黄荣谊 任小明 |
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| 作者单位： | 安庆师范学院化学化工学院,功能配合物安徽省重点实验室,安庆,246003 |
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| 基金项目： | 国家自然科学基金资助项目，安徽省学术技术带头人科研基金资助项目 |
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| 摘 要： |
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| 关 键 词： | 锌的配位聚合物 晶体结构 柔性配体 荧光性质 |
Synthesis, Crystal Structure and Luminescent Property of Coordination Polymer [Zn(PDA)(obix)] |
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| ZHU Kun,XU Huan-Min,LIU Guang-Xiang,HUANG Rong-Yi and REN Xiao-Ming.Synthesis, Crystal Structure and Luminescent Property of Coordination Polymer [Zn(PDA)(obix)][J].Chinese Journal of Inorganic Chemistry,2009,25(9):1677-1681. |
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| Authors: | ZHU Kun XU Huan-Min LIU Guang-Xiang HUANG Rong-Yi and REN Xiao-Ming |
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| Institution: | Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246003,Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246003,Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246003,Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246003 and Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, Anhui 246003 |
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| Abstract: | Hydrothermal reaction between 1,4-phenylenediacetic acid (H2PDA) and Zn(NO3)2·6H2O at the presence of the second ligand of 1,2-bis((1H-imidazol-1-yl) methyl)benzene (obix) yields a new 2D metal-organic coordination polymer Zn(PDA)(obix)] (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermal analysis. Complex 1 presents a two-dimensional (2D) sheet structure and displays strong luminescent emission at room temperature. CCDC: 716984. |
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| Keywords: | crystal structure flexible ligand luminescence |
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