Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned ironIII cyanide precursor |
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| Authors: | Kim Jae Il Yoo Houng Sik Koh Eui Kwan Kim Hyoung Chan Hong Chang Seop |
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| Affiliation: | Department of Chemistry, Korea University, Seoul 136-713, Korea. |
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| Abstract: | ![]()
A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN)(3)]- (1), and a zigzag chain, [Fe(pzcq)(CN)(3)][Mn(salen)].4H(2)O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature. |
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