| Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O |
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| 引用本文： | 陈文通,郭国聪,曾锡瑞,李新发,方小牛,匡汉茂,刘冬生,刘利民.Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O[J].结构化学,2007(10). |
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| 作者姓名： | 陈文通 郭国聪 曾锡瑞 李新发 方小牛 匡汉茂 刘冬生 刘利民 |
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| 作者单位： | College of Chemistry and Chemical Engineering Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，College of Chemistry and Chemical Engineering，Jiangxi Province Key Laboratory of Coordination Chemistry，Jinggangshan University，Ji'an，Jiangxi 343009，China，Fuzhou，Fujian 350002，China，Ji'an，Jiangxi 343009，China，Ji'an，Jiangxi 343009，China，Ji'an，Jiangxi 343009，China，Ji'an，Jiangxi 343009，China，Ji'an，Jiangxi 343009，China，Ji'an，Jiangxi 343009，China |
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| 基金项目： | the doctor scientific research start-up foundation of Jinggangshan University, China |
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| 摘 要： | The title compound (4,4′-H2bipy)CdBr4]·H2O 1 has been synthesized via hydrothermal reaction and characterized by X-ray diffraction. The crystal belongs to monoclinic,space group P21/c with a=8.260(3),b=23.926(7),c=9.774(2),β=106.777(9)o,C10H12Br4CdN2O,Mr=608.26,V=1849.4(9)3,Z=4,Dc=2.185 g/cm3,S=1.005,μ(MoKα) =9.814 mm–1,F(000)=1128,R=0.0646 and wR=0.0989. The crystal structure analysis of 1 reveals that the title compound features an isolated structure,based on discrete 4,4′-H2bipy moieties and lattice water molecules which are linked by hydrogen bonds together with tetra-hedral cadmium atoms terminally coordinated by four bromine atoms.
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Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O |
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| CHEN Wen-Tonga GUO Guo-Congb ZENG Xi-Ruia LI Xin-Faa FANG Xiao-Niua KUANG Han-Maoa LIU Dong-Shenga LIU Li-Mina a.Synthesis and Crystal Structur of (4,4′-H_2bipy)[CdBr_4]·H_2O[J].Chinese Journal of Structural Chemistry,2007(10). |
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| Authors: | CHEN Wen-Tonga GUO Guo-Congb ZENG Xi-Ruia LI Xin-Faa FANG Xiao-Niua KUANG Han-Maoa LIU Dong-Shenga LIU Li-Mina a |
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| Abstract: | The title compound (4,4′-H2bipy)CdBr4]·H2O 1 has been synthesized via hydrothermal reaction and characterized by X-ray diffraction. The crystal belongs to monoclinic,space group P21/c with a=8.260(3),b=23.926(7),c=9.774(2),β=106.777(9)o,C10H12Br4CdN2O,Mr=608.26,V=1849.4(9)3,Z=4,Dc=2.185 g/cm3,S=1.005,μ(MoKα) =9.814 mm–1,F(000)=1128,R=0.0646 and wR=0.0989. The crystal structure analysis of 1 reveals that the title compound features an isolated structure,based on discrete 4,4′-H2bipy moieties and lattice water molecules which are linked by hydrogen bonds together with tetra-hedral cadmium atoms terminally coordinated by four bromine atoms. |
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| Keywords: | cadmium crystal structure halide hydrothermal |
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