| 杯[4]芳烃锥形骨架在光学受体识别中的作用 |
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| 引用本文： | 马会民,马泉莉,苏美红,聂丽华,谷涵,熊少祥,梁树权.杯[4]芳烃锥形骨架在光学受体识别中的作用[J].分析化学,2002,30(9):1042-1047. |
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| 作者姓名： | 马会民 马泉莉 苏美红 聂丽华 谷涵 熊少祥 梁树权 |
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| 作者单位： | 中国科学院化学研究所分子科学中心,北京,100080 |
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| 基金项目： | 国家自然科学基金 (No .2 0 175 0 31,2 0 0 35 0 10 )，国家分子科学中心基金 (CMS CX2 0 0 10 4)资助项目 |
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| 摘 要： | 比较研究了铜、镍的杯4]芳烃光学受体及其单体的分析性能，并进一步探讨了杯4]芳烃的锥形骨架在分子识别中的作用。结果表明，通过分子设计，将杯4]芳烃锥形骨架合理地引至光学受体中，可以起到立体屏障作用，能有效阻止其它客体在一些方向上靠近配位反应点所带来的干扰，从而对客体的选择性识别提供重要贡献。
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| 关 键 词： | 光学受体 杯[4]芳烃 锥形骨架 立体效应 镍显色受体 铜荧光受体 分子识别 光学识别试剂 |
The Role of Calix[4]arene Skeleton with Cone Conformation in Recognition of Spectroscopic Acceptors |
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| Ma Huimin ,Ma Quanli,Su Meihong,Nie Lihua,Gu Han,Xiong Shaoxiang,Liang Shuquan.The Role of Calix[4]arene Skeleton with Cone Conformation in Recognition of Spectroscopic Acceptors[J].Chinese Journal of Analytical Chemistry,2002,30(9):1042-1047. |
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| Authors: | Ma Huimin Ma Quanli Su Meihong Nie Lihua Gu Han Xiong Shaoxiang Liang Shuquan |
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| Institution: | Ma Huimin *,Ma Quanli,Su Meihong,Nie Lihua,Gu Han,Xiong Shaoxiang,Liang Shuquan |
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| Abstract: | In order to understand further the role of calixarene skeleton with cone conformation in recognition of spectroscopic acceptors, a comparative study was made on calixarenes and their monomers, including the design and properties of calixarene-based chromoionophore for Ni 2+ and especially fluorescent acceptor for Cu 2+. The results show that calixarene skeleton with cone conformation, introduced rationally into a designed acceptor, may serve as a shielding or covering unit, which prohibits other guests from approaching reaction sites at least in one direction and can thus make a contribution to the selectivity. |
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| Keywords: | Calixarene skeleton with cone conformation steric effect nickel chromoionophore fluorescent copper acceptor |
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