The unusual coordination chemistry of phosphorus-rich linear and cyclic oligophosphanide anions |
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| Authors: | Santiago Gómez-Ruiz Evamarie Hey-Hawkins |
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| Institution: | 1. Departamento de Química Inorgánica y Analítica, E.S.C.E.T. Universidad Rey Juan Carlos, Calle Tulipán s/n, 28933, Móstoles, Spain;2. Institut für Anorganische Chemie der Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany |
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| Abstract: | In this review, the synthesis, reactivity and properties of linear and cyclic oligophosphanides are described. Specifically the structures and versatile reactivity of the anionic ligands (P4R4)2? (R = But, Ph, Mes), (P4HR4)? (R = Ph and Mes) and cyclo-(P5But4)? towards main group and transition metal complexes is elucidated. In addition, potential application of metal oligophosphanides as precursors for the preparation of metal phosphides is also briefly discussed. |
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