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Photochemical synthesis of gold–polyethylenglycol core–shell nanoparticles
Authors:J Amici  M Sangermano  E Celasco  Y Yagci
Institution:aPolitecnico di Torino, Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Corso Duca degli Abruzzi 24, 10125 Torino, Italy;bIstanbul Technical University, Department of Chemistry, Maslak, 34469 Istanbul, Turkey
Abstract:A new, fast and convenient method for the preparation of gold–polyethylenglycol core–shell nanoparticles in water was described. The method pertains to the concomitant redox and polymerization reactions of the acrylic formulation induced by photochemically generated radicals from the photoinitiator, 2-hydroxy-2-methyl-1-phenyl-1-propanone. The nanoparticles were characterized by using Dynamic Light Scattering (DLS), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). Homogenous core–shell structured nanoparticles obtained this way are expected to find important applications in bio-medical fields.
Keywords:Core&ndash  shell nanoparticles  Gold nanoparticles  Acrylic resin  Photopolymerization  Electron transfer
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