Synthesis of PCL–graft–PS by combination of ROP, ATRP, and click chemistry |
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Authors: | Vincent Darcos Hadil Al Tabchi Jean Coudane |
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Institution: | Max Mousseron Institute of Biomolecules, UMR CNRS 5247, University of Montpellier 1, University of Montpellier 2, Faculty of Pharmacy, 15 Avenue Charles Flahault, BP 14491, 34093 Montpellier Cedex 5, France |
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Abstract: | Poly(ε-caprolactone)–graft–polystyrenes were successfully synthesized by grafting an azide end-functionalized polystyrene onto a PCL backbone with multiple pendant alkyne moieties using a “click” chemistry reaction. Both precursors, the PCL backbone and the PS side chains, were prepared separately by two different living/controlled mechanisms, ring-opening polymerisation and ATRP, respectively. Molecular weights, polydispersity indexes, and chemical compositions of the backbone and branches were controlled. The subsequent copper-catalysed Huisgen 1,3-dipolar cycloaddition of PS onto PCL was achieved at room temperature with high conversion. However, a bimodal molecular weight distribution was observed in size exclusion chromatography due to the presence of unreacted PS. Nevertheless, crude product was purified by selective fractionation in cyclohexane to achieve pure graft copolymers. |
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Keywords: | Caprolactone PCL Graft polyester Ring-opening polymerisation ATRP Click chemistry |
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