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Solvent-free ketone hydrogenations catalyzed by molybdenum complexes |
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| Authors: | Kimmich Barbara F M Fagan Paul J Hauptman Elisabeth Bullock R Morris |
| Affiliation: | Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973, USA. |
| Abstract: | Et2C=O is hydrogenated under solvent-free conditions using a catalyst prepared by hydride abstraction from HMo(CO)2[eta5:eta1-C5H4(CH2)(2)PCy2]; the catalyst functions at low catalyst loadings (< 0.4 mol%). |
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