Electrochromic properties of anodically grown mixed V2O5–TiO2 nanotubes |
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Authors: | Yang Yang Doohun Kim Patrik Schmuki |
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Institution: | aDepartment of Materials Science and Engineering, WW4-LKO, University of Erlangen-Nuremberg, Martensstr. 7, D-91058 Erlangen, Germany |
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Abstract: | Mixed V2O5–TiO2 nanotube arrays were fabricated by self-organizing anodization of different Ti–V alloys. The mixed oxide nanotubes show switchable V-oxidation states and strong cathodic coloration. Already a low V content of ≈ 0.2 at.% significantly increases the electrochromic switching properties. Using a sample with 3 at.% V, very high electrochromic contrast can be established and a significantly lower switching onset voltage than for pure TiO2 nanotubes is observed. At high V contents, although charge storage is increased, the improvement of contrast is diminished due to the strong background color of the sample. |
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Keywords: | Nanotubes Electrochromic Titanium dioxide Vanadium pentoxide |
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