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The stereochemistry of enolate formation in THF-hexane mixtures
Authors:Michael J. Munchhof  Clayton H. Heathcock
Affiliation:

Department of Chemistry, University of California, Berkeley, CA 94720 USA

Abstract:
The effect of solvent on the stereochemistry of deprotonation of 4-heptanone in THF-hexane mixtures is plotted in the figure on the following page. The E/Z ratio varies from 1.5 in pure THF to 0.7 in 90% hexane.
Keywords:
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