| Ni(pz)4Cl2型络合物的光、热、磁性质的研究 |
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| 引用本文： | 颜占先,周小清,戴薇,陈次星.Ni(pz)4Cl2型络合物的光、热、磁性质的研究[J].物理化学学报,1996,12(11):995-1000. |
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| 作者姓名： | 颜占先 周小清 戴薇 陈次星 |
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| 作者单位： | Department of Physics,Hunan Jishou University,Jishou 416000 |
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| 摘 要： | 利用ｄ＾８（Ｄ４ｈ）全组态混合统一晶场理论计算了Ｎｉ（ｐｚ）４Ｃｌ２型物中Ｎｉ＾２＋离子的吸收光谱、顺磁磁性 率及Ｓｃｈｏｔｔｋｙ热容。理论结果与实验一致。
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| 关 键 词： | Ni(pz)4Cl2 吸收光谱 磁化率 Schottky热容 |
| 收稿时间： | 1996-05-29 |
| 修稿时间： | 1996-08-09 |
Theoretical Research on Optical, Thermal and Magnetic Properties of Ni(pz)_4Cl_2 Complex |
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| Yan Zhanxian,Zhou Xiaoqing,Dai Wei,Chen Cixing.Theoretical Research on Optical, Thermal and Magnetic Properties of Ni(pz)_4Cl_2 Complex[J].Acta Physico-Chimica Sinica,1996,12(11):995-1000. |
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| Authors: | Yan Zhanxian Zhou Xiaoqing Dai Wei Chen Cixing |
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| Institution: | Department of Physics,Hunan Jishou University,Jishou 416000 |
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| Abstract: | In this paper, we have calculated analyzed theoretically the absorption spectra, the low-temperature Schottky heat capacity and the paramagnetic sllsceptibility of Ni2 ions in Ni(pz)4Cl2 (pz=Pyrazole) complex, by using the complete configuration mixing unified crystal field theory for d8(D4h*), and the theoretical results agree with the experimental data very well. Thus we can give a complete and reasonable theortical interpretation of the optical, thermal and magnetic properties of the Ni2 ions in Ni(pz)4Cl2 complex. |
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| Keywords: | Ni(pz)_4Cl_2 Absorption spectra Susceptibility Schottky heat capacity |
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