Optical and chromaticity characteristics of palladium(II) complex with 1-nitroso-2-naphthol-3,6-disulfonic acid |
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Authors: | V. M. Ivanov T. O. Samarina V. N. Figurovskaya |
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Affiliation: | 1.Division of Analytical Chemistry,Moscow State University,Moscow,Russia |
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Abstract: | Optimal conditions of complexation palladium(II) with 1-nitroso-naphthol-3,6-disulfonic acid were found by the spectrophotometric method (an optimum interval pH 1.2–3.8, a five-multiple surplus reagent). The analytical characteristics of a complex in an interval concentration of palladium(II) (0.94–8.59) × 10−5 M are determined, ɛ = (9.80 ± 0.02) × 103 (n = 9, P = 0.95). The function and molar coefficient of chromaticity are determined. The most sensitive functions are G [(7.6 ± 0.1) × 105] and Z [(5.6 ± 0.2) × 105] (n = 5, P = 0.95). |
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