161Dy Time‐Domain Synchrotron Mössbauer Spectroscopy for Investigating Single‐Molecule Magnets Incorporating Dy Ions |
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| Authors: | Lena Scherthan,Sebastian F. M. Schmidt,Hendrik Auerbach,Tim Hochd rffer,Juliusz A. Wolny,Wenli Bi,Jiyong Zhao,Michael Y. Hu,Tom Toellner,E. Ercan Alp,Dennis E. Brown,Christopher E. Anson,Annie K. Powell,Volker Schü nemann |
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| Affiliation: | Lena Scherthan,Sebastian F. M. Schmidt,Hendrik Auerbach,Tim Hochdörffer,Juliusz A. Wolny,Wenli Bi,Jiyong Zhao,Michael Y. Hu,Tom Toellner,E. Ercan Alp,Dennis E. Brown,Christopher E. Anson,Annie K. Powell,Volker Schünemann |
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| Abstract: | Time‐domain synchrotron Mössbauer spectroscopy (SMS) based on the Mössbauer effect of 161Dy has been used to investigate the magnetic properties of a DyIII‐based single‐molecule magnet (SMM). The magnetic hyperfine field of [Dy(Cy3PO)2(H2O)5]Br3?2 (Cy3PO)?2 H2O?2 EtOH is with B0=582.3(5) T significantly larger than that of the free‐ion DyIII with a 6H15/2 ground state. This difference is attributed to the influence of the coordinating ligands on the Fermi contact interaction between the s and 4f electrons of the DyIII ion. This study demonstrates that 161Dy SMS is an effective local probe of the influence of the coordinating ligands on the magnetic structure of Dy‐containing compounds. |
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| Keywords: | Dysprosium Einzelmolekü lmagnete Lanthanoide Magnetische Eigenschaften Mö ß bauer-Spektroskopie |
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