C-H activation of ethers and alkanes by germylene-aryl halide complexes |
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| Authors: | Miller Karla A Bartolin Jeffrey M O'Neill Rory M Sweeder Ryan D Owens Thomas M Kampf Jeff W Banaszak Holl Mark M Wells Norman J |
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| Affiliation: | University of Michigan, Department of Chemistry, Ann Arbor, MI 48109, USA. |
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| Abstract: | ![]()
Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques. |
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