| 中国南海海绵中19-methoxy-scalarin立体构型的确定 |
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| 引用本文： | 李敏一,李林,邓志威,邱彦,林文翰.中国南海海绵中19-methoxy-scalarin立体构型的确定[J].波谱学杂志,2004,21(3):323-329. |
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| 作者姓名： | 李敏一 李林 邓志威 邱彦 林文翰 |
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| 作者单位： | 北京师范大学,分析测试中心,北京,100875;北京大学,天然药物及仿生药物国家重点实验室,北京,100083 |
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| 摘 要： | 对中国南海海绵中的新化合物19-methoxy-scalarin进行1H和13C NMR谱的全归属, 并运用“激发雕刻”技术，利用1D GOESY实验确定该化合物立体构型。实验结果亦表明1D GOESY实验选择性好，提供的信息更加直观、清晰，是化合物立体结构确定的好方法。
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| 关 键 词： | 核磁共振 南海海绵 19-methoxy-scalarin GOESY 激发雕刻 |
| 收稿时间： | 2004-02-27 |
NMR DETERMINATION OF THE CONFIGURATION OF 19-METHOXY-SCALARIN ISOLATED FROM HYRTIOS ERECTUS |
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| Abstract.NMR DETERMINATION OF THE CONFIGURATION OF 19-METHOXY-SCALARIN ISOLATED FROM HYRTIOS ERECTUS[J].Chinese Journal of Magnetic Resonance,2004,21(3):323-329. |
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| Authors: | Abstract |
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| Institution: | 1.Analytical & Testing Center, Beijing Normal University, Beijing 100875,China;;
2.State Key Laboratory of Natural and Biomimetic drugs, Beijing University, Beijing 100083,China |
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| Abstract: | A new diterpenoid, 19-methoxy-scalarin, was isolated from marine sponge Hyrtios
erectus. Its structure was determined by 1D and 2D NMR spectroscopy. In combination with
the "excitation sculpting" technique, 1D GOESY was used for its configuration determination.
The experimental results show that, compared to the commonly used NOE difference method,
1D GOESY provides a more direct and easy way for configuration determination. |
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| Keywords: | 19-methoxy-scalarin GOESY NMR Hyrtios erectus 19-methoxy-scalarin GOESY excitation sculpting |
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