| 铑催化不对称1,4-共轭加成反应的研究进展 |
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| 引用本文： | 王欢,杨定乔,莫海洪. 铑催化不对称1,4-共轭加成反应的研究进展[J]. 有机化学, 2007, 27(7): 806-818 |
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| 作者姓名： | 王欢 杨定乔 莫海洪 |
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| 作者单位： | 华南师范大学化学与环境学院,广州,510006 |
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| 基金项目： | 广东省自然科学基金（No.04010404）资助项目. |
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| 摘 要： | 铑催化不对称1,4-共轭加成反应是一种非常有效的碳-碳键形成方法. 本文综述了近年来铑催化不对称1,4-共轭加成反应的研究进展, 包括α,β-不饱和酮、酯、酰胺、醛和砜等与某些亲核试剂的1,4-共轭加成反应.
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| 关 键 词： | 铑催化 不对称 亲核试剂 1,4-共轭加成 |
| 收稿时间： | 2006-07-26 |
| 修稿时间： | 2006-07-262006-10-18 |
Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions |
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| WANG Huan,YANG Ding-Qiao,MO Hai-Hong. Progress in Rhodium-Catalyzed Asymmetric 1,4-ConjugateAddition Reactions[J]. Chinese Journal of Organic Chemistry, 2007, 27(7): 806-818 |
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| Authors: | WANG Huan YANG Ding-Qiao MO Hai-Hong |
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| Affiliation: | School of Chemistry and Environment, South China Normal University, Guangzhou 510006 |
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| Abstract: | Rhodium-catalyzed asymmetric 1,4-conjugate addition reaction is one of the most efficient methods for the carbon-carbon bond formation. In this paper, the recent progress in rhodium-catalyzed asymmetric 1,4-conjugate addition reactions is reviewed. Asymmetric 1,4-conjugate additions of α,β-unsaturated ketones, esters, amides, aldehydes, sulfones and so on with some nu-cleophiles are presented. |
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| Keywords: | rhodium-catalyzed asymmetric nucleophile 1,4-conjugate addition |
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