Abstract: | N-benzylanyline single crystals are grown, and X-ray diffraction probing of their structure allows their symmetry to be attributed to the C2h.5 phase. Polarized Raman studies of these crystals allow the frequencies of lattice phonons to be estimated and their symmetry to be established. The abnormal behavior of the two lowest-frequency Ag symmetry soft modes, the condensation of which is not detected below the melting point (36–38°C), is noted. The possibility of a high-temperature virtual phase transition and praphase is discussed. Theory group consideration of the praphase allows determination of its symmetry and the symmetry of phonons related to the virtual phase transition. |