Molecular structure of AlH3[N(CH2CH2)3CH]2 |
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| Authors: | C. Jeff Harlan Simon G. Bott Andrew R. Barron |
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| Affiliation: | (1) Department of Chemistry, Rice University, Houston, Texas, 77005;(2) Department of Chemistry, University of Houston, Houston, Texas, 77204 |
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| Abstract: | ![]()
Reaction of AlH3[N(CH2CH2)3CH] with hexamethyltrisiloxane, (OSiMe2)3, gives rise to the bis-quinuclidine complex AlH3[N(CH2CH2)3CH]2, which has been characterized by 1H and 13C NMR spectroscopy and X-ray crystallography. The molecular structure of AlH3[N(CH2CH2)3CH]2 consists of a trigonal bipyramidal aluminum with axial coordination of the quinuclidine ligands. Crystal data: orthorhombic, space group Pbcn, a = 10.6895(9), b = 12.266(1), c = 12.3794(9) Å, V = 1623.2(2) Å3, and Z = 4. |
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| Keywords: | Crystal structure aluminum hydride complex quinuclidine |
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