Reaction of 1,2,4-triazole-3-thione with acetylene |
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Authors: | G G Skvortsov B V Trzhtsinskaya L F Teterina V K Voronov M N Popova |
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Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, 664033 Irkutsk |
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Abstract: | A mixture of 1,2,4-triazol-3-yl vinyl sulfide and N,S-divinyl derivatives is formed in the reaction of 1,2,4-triazole-3-thione with acetylene under pressure. The mixture of N,S-divinyl derivatives was separated into two isomers by gas-liquid chromatography. The hydrogenation, polymerization, and complexing of 1,2,4-triazol-3-yl vinyl sulfide were studied.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1561–1563, November, 1977. |
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