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Thermodynamics of Surface Tension: Application to Electrolyte Solutions
Authors:Yan Levin
Institution:(1) Instituto de Física, Universidade Federal do Rio Grande do Sul, Caixa Postal 15051, CEP 91501-970 Porto Alegre, RS, Brazil
Abstract:In this contribution to the special issue of the Journal of Statistical Physics dedicated to Michael Fisher on his 70th birthday, I shall review two thermodynamically distinct routes for obtaining the interfacial tension of liquid-vapor interfaces in mixtures. A specific application to the calculation of excess surface tension of aqueous electrolyte solutions will be presented.
Keywords:Surface tension  electrolyte  interface  adsorption isotherm
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