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A simplified procedure for the determination of butyltin species in water
Authors:A H Chapman  A Samuel
Abstract:A method is described for the analysis of solutions containing inorganic tin and butyltin compounds. It can be used to determine total tin at a concentration of 20 ng dm?3 using a 5 dm3 sample. The method is based on solvent extraction with dichloromethane containing tropolone and determination of the tin as inorganic tin by atomic absorption spectroscopy using electrothermal atomization. The extracted butyltin compounds can be separated by paper chromatography and the tin content of the individual spot determined as above. Observations on the stability of butyltin compounds in water at the ~2 mg dm?3 (Sn) are included.
Keywords:Butyltin analysis  atomic absorption  electrothermal analysis  paper chromatography
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