Coordination polymers of gold(I) with dithiolate and diphosphine ligands |
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| Authors: | Hunks William J Jennings Michael C Puddephatt Richard J |
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| Institution: | Department of Chemistry, University of Western Ontario, London, ON, Canada N6A 5B7. |
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| Abstract: | The first neutral, hybrid organic-inorganic coordination polymers with linear gold(I) centres in the backbone have the formula X(OCH2CH2O2CCH2SAu)2(mu-dppee)]n, X = 1,4-C6H4 or C10H6, dppee = trans-bis(diphenylphospino)ethylene, are easily formed by self-assembly during crystallization from macrocyclic isomers (n = 1), and form sheet structures anchored by secondary Au...S and S...S interactions in the solid state. |
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