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Intramolecular dealkylation of chelating diamines with Ru(II) complexes |
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| Authors: | Morilla M Esther Morfes Galanda Nicasio M Carmen Belderrain Tomás R Mar Díaz-Requejo M Graiff Claudia Tiripicchio Antonio Sánchez-Delgado Roberto Pérez Pedro J |
| Affiliation: | Departamento de Química y Ciencia de los Materiales, Universidad de Huelva, Carretera de Palos de la Frontera s/n, E-21819 Huelva, Spain. |
| Abstract: | N,N, N',N'-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 degrees C to afford chelating amine ligands which contains one or two N-H functionalities. |
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