| Synthesis and Crystal Structure of a Novel Two-dimensional Supramolecular Complex Ni（C6H7N）2（SCN）2（H2O）2 |
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| 引用本文： | 谭小娜,车云霞,郑吉民. Synthesis and Crystal Structure of a Novel Two-dimensional Supramolecular Complex Ni（C6H7N）2（SCN）2（H2O）2[J]. 结构化学, 2006, 25(3): 358-362 |
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| 作者姓名： | 谭小娜 车云霞 郑吉民 |
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| 作者单位： | Department of Chemistry Nankai University，Department of Chemistry Nankai University，Department of Chemistry Nankai University，Tianjin 300071 China，Tianjin 300071 China，Tianjin 300071 China |
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| 摘 要： | 1 INTRODUCTION Supramolecular chemistry is based on the notion of creating novel structural and functional extended systems using noncovalent interactions between prefabricated molecular or ionic building blocks[1]. More recently, the design of supramolecular architec- tures by self-assembly of small building blocks has become a major research area[2, 3] due to their poten- tial applications in many fields such as selective clathration[4, 5], molecular recognition[6, 7], catalysis[8, 9] a…
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| 关 键 词： | 镍（Ⅱ）配合物 合成 晶体结构 二维空间超分子化合物 氢键 Ni（C6H7N）2（SCN）2（H2O）2 |
Synthesis and Crystal Structure of a Novel Two-dimensional Supramolecular Complex Ni(C6H7N)2(SCN)2(H2O)2 |
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| TAN Xiao-Na,CHE Yun-Xia,ZHENG Ji-Min. Synthesis and Crystal Structure of a Novel Two-dimensional Supramolecular Complex Ni(C6H7N)2(SCN)2(H2O)2[J]. Chinese Journal of Structural Chemistry, 2006, 25(3): 358-362 |
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| Authors: | TAN Xiao-Na CHE Yun-Xia ZHENG Ji-Min |
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| Affiliation: | Department of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | A novel nickel(II) complex Ni(C6H7N)2(SCN)2(H2O)2 (C14H18N4NiO2S2, Mr = 397.15) has been synthesized and structurally characterized by X-ray analysis. The crystal is of monoclinic, space group P21/c with a = 9.212(2), b = 13.132(3), c = 7.8794(19)(A), β = 99.142(3)o, Z = 2, V = 41.1(4)(A)3, Dc = 1.402 g/m3, μ(MoKα) = 1.264 mm-1, F(000) = 412, R1 = 0.0303 and wR2 = 0.0794 for 1387 observed reflections (I > 2σ(I)). The title complex shows a 2-D network structure extended by twelve-membered Ni2O2H2S2C2N2 ring and ten-membered NiO2H3S2CN ring. |
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| Keywords: | crystal structure nickel(II) complex synthesis hydrogen-bonding |
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