Planar beta-linked oligothiophenes based on thieno[3,2-b]thiophene and dithieno[3,2-b:2',3'-d]thiophene fused units |
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Authors: | San Miguel Lidaris Porter William W Matzger Adam J |
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Institution: | Department of Chemistry and the Macromolecular Science and Engineering Program, University of Michigan, 930 North University, Ann Arbor, MI 48109-1055, USA. |
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Abstract: | A series of planar beta-linked oligothiophenes based on thieno3,2-b]thiophene and dithieno3,2-b:2',3'-d]thiophene fused units were synthesized. The optical data indicate a blue shift of the absorption maximum in comparison to the alpha-linked analogues due to cross-conjugation between fused rings. The crystal structures of 3,3'-bi(thieno3,2-b]thiophene) and 3,3';6',3"-ter(thieno-3,2-b]thiophene) reveal edge-to-face pi-stacked dimer motifs, whereas the crystal structure of 3,3'-bis(dithieno3,2-b:2',3'-d]thiophene) consists of face-to-face pi-stacked molecules. structure: see text] |
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