New linear chain compounds based on an aza macrocyclic copper(II) complex with halide ions |
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Authors: | Ya. D. Lampeka I. M. Maloshtan Ph. Lightfoot R. W. Hay |
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Affiliation: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, 252039 Kiev, Ukraine;(2) School of Chemistry, The Purdie Building, University of St. Andrews, KY16 9ST, Fife, Scotland UK |
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Abstract: | ![]() We have shown by X-ray diffraction analysis that participation of functional groups on the macrocycle in formation of hydrogen bonds promotes formation of crystal lattices with previously undescribed linear polymer chains ... Cu ... Hal ... Cu ... Hal ... We have used spectral methods to confirm the presence of a Cu-Hal interaction, which makes these compounds promising for design of new materials with anisotropic physical properties. Deceased Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 34, No. 6, pp. 355–359, November–December 1998. |
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