1. Departamento de Química Orgánica I, Facultad de Química, Universidad Complutense de Madrid, 28040 Madrid (Spain), Fax: (+34)?91‐3944103;2. Instituto de Química Orgánica General, Consejo Superior de Investigaciones Científicas, CSIC, Juan de la Cierva 3, 28006 Madrid (Spain), Fax: (+34)?91‐5644853
Abstract:
Positive discrimination : Chemo‐ and regioselective palladium‐catalyzed cycloetherification of allendiols, namely β,γ‐ and γ,δ‐allendiols, may occur by judicious choice of palladium‐catalyzed conditions owing to their potential ability to discriminate between both nucleophilic sites (see scheme).
