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Ti0.99Pd0.01O2−δ: A New Pt‐free Catalyst for High Rates of H2+O2 Recombination with High CO Tolerant Capacity
Authors:Sudhanshu Sharma  Manjanath S. Hegde Prof.
Affiliation:Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore‐560012 (India), Fax: (+91)?080‐2360‐1310
Abstract:
A platinum‐free H 2 /O 2 recombination catalyst , Ti0.99Pd0.01O2?δ, is synthesized by a solution combustion method where Pd2+ ions adsorb protonic H2δ+ ion and oxygen on the oxide ion vacancy sites (see picture). The rate of H2+O2 recombination at 50 °C is 15 μmoles g?1 s?1, which is much higher than that of Pt‐containing catalysts.
image

Keywords:carbon monoxide  catalysis  H2+O2 recombination  kinetics  palladium
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