|
|||||
|
|
Post‐Modification of meso–meso‐Linked Porphyrin Arrays by Iridium and Rhodium Catalyses for Tuning of Energy Gap |
|
| Authors: | Jinping Chen Dr. Naoki Aratani Dr. Hiroshi Shinokubo Prof. Dr. Atsuhiro Osuka Prof. Dr. |
| Affiliation: | 1. Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo‐ku, Kyoto 606‐8502 (Japan), Fax: (+81)?75‐753‐3970;2. Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa‐ku, Nagoya 464‐8603 (Japan), Fax: (+81)52‐789‐5113 |
| Abstract: | Skillfully attached! meso–meso‐Linked diporphyrins can be efficiently and selectively functionalized with multiple unsaturated carboxylic acid groups through iridium and rhodium catalyses. This post‐modification strategy allows fine‐tuning of energy levels of each porphyrin unit.  |
| Keywords: | C?C coupling C?H activation iridium porphyrinoids rhodium |