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Fine‐Tuning Mesochannel Orientation of Organically Functionalized Mesoporous Silica Nanoparticles
Authors:Shy‐Guey Wang  Chia‐Wen Wu Prof.  Kwunmin Chen Prof.  Victor S.‐Y. Lin Prof.
Affiliation:1. Department of Chemistry, U.S. DOE Ames Laboratory, Iowa State University, Ames, Iowa 50011‐3111 (USA), Fax: (+1)?515‐294‐0105;2. Department of Chemistry, National Taiwan Normal University, No. 88, Sec. 4, Ting‐Chow Rd, Taipei, Taiwan, 11677 (Taiwan), Fax: (+886)?2‐2932‐4249;3. S.‐G. Wang and C.‐W. Wu contributed equally to this paper.;4. Department of Chemical Engineering, National Taiwan University, No.1, Sec. 4, Roosevelt Rd. Taipei, Taiwan 106 (Taiwan), Fax: (+886)?2‐2362‐3040
Abstract:Three orientations to choose from : 2D hexagonal organically functionalized mesoporous silica nanoparticles with tunable mesochannel orientation (straight, helical, and radial mesochannels) were synthesized through a simple addition of various amounts of ureidopropyltrimethoxylsilane (UDPTMS) in the condensation of tetraorthosilicate (TEOS) in aqueous solution.
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Keywords:co‐condensation  mesoporous materials  morphology control  nanoparticles  silica
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