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Synthesis and Structure of an Extremely Air‐Stable Binuclear Hafnocene Perfluorooctanesulfonate Complex and Its Use in Lewis Acid‐Catalyzed Reactions
Authors:Renhua Qiu  Guoping Zhang  Yuyang Zhu  Xinhua Xu  Lingling Shao  Yinhui Li  Delie An  Shuangfeng Yin
Affiliation:College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (China), Fax: (+86)?731‐511‐8161
Abstract:
Stable complexes : An extremely air‐stable μ2‐hydroxy‐bridged binuclear hafonocene perfluorooctanesulfoante complex shows high catalytic efficiency in Lewis acid‐catalyzed reactions, such as esterification, Friedel–Crafts acylation, the Mukaiyama aldol reation, and the allylation of aldehyde (see scheme).
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Keywords:hafnocenes  homogeneous catalysis  Lewis acids  perfluorooctanesulfonate
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