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Large Entropic Effect in Flexible Crystalline Media for Gas Separation |
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| Authors: | Satoshi Takamizawa Masa‐aki Kohbara Ryosuke Miyake |
| Abstract: | Changing channels : The novel dynamic gas‐separation mechanism is demonstrated by a GC study for a flexible single crystal Cu2(bza)4(pyz)]n, 1 . The single‐crystal host 1 , because of its flexibility, can separate various gases by adjusting its channel structure according to the features of the guest gaseous molecules.  |
| Keywords: | adsorption crystal structure gas chromatography microporous materials physisorption |