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Inside Cover: Bifunctional Dendrimers: From Robust Synthesis and Accelerated One‐Pot Postfunctionalization Strategy to Potential Applications (Angew. Chem. Int. Ed. 12/2009)
Authors:Per Antoni Dr.  Yvonne Hed  Axel Nordberg  Daniel Nyström Dr.  Hans von Holst Prof.  Anders Hult Prof.  Michael Malkoch Prof.
Affiliation:1. Royal Institute of Technology, School of Chemistry and Chemical Science, Division of Coating Technology, Teknikringen 56‐58, 10044 Stockholm (Sweden), Fax: (+46)?790‐8283;2. Royal Institute of Technology, School of Technology and Health, Neuronic Engineering, Huddinge (Sweden) and Karolinska Institute, Department of Clinical Neuroscience, Stockholm (Sweden)
Abstract:
By taking advantage of “click” chemistry's chemoselective nature, a new platform of bifunctional AB2C dendrimers, having acetylene/azide groups anchored within the interior and hydroxy groups on the periphery, has been realized. In their Communication on page 2126 ff. M. Malkoch and co‐workers reveal a simple synthetic route for two sets of frameworks. To illustrate the utility of AB2C dendrimers they were used in a one‐pot postfunctionalization protocol, in the development of dendritic nanoparticles, and in the formation of hydrogels.
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Keywords:click chemistry  dendrimers  gels  nanoparticles  synthetic methods
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