Identification of Hydroxyl on Ni(111) |
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Authors: | Junjun Shan Aart W Kleyn Prof Dr Ludo B F Juurlink Dr |
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Institution: | 1. Leiden Institute of Chemistry, Universiteit Leiden, Gorlaeus Laboratories, PO Box 9502, 2300 RA Leiden (The Netherlands), Fax: (+31)?71?527?4537;2. FOM Institute for Plasma Physics Rijnhuizen, PO Box 1207, 3430 BE, Nieuwegein (The Netherlands) |
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Abstract: | Hydroxyl (OH) is identified and characterized on the Ni(111) surface by high‐resolution electron energy loss spectroscopy. We find clear evidence of stretching, bending, and translational modes that differ significantly from modes observed for H2O and O on Ni(111). Hydroxyl may be produced from water by two different methods. Annealing of water co‐adsorbed with atomic oxygen at 85 K to above 170 K leads to the formation of OH with simultaneous desorption of excess water. Pure water layers treated in the same fashion show no dissociation. However, the exposure of pure water to 20 eV electrons at temperatures below 120 K produces OH in the presence of adsorbed H2O. In combination with temperature‐programmed desorption studies, we show that the OH groups recombine between 180 and 240 K to form O and immediately desorbing H2O. The lack of influence of co‐adsorbed H2O at 85 K on the O? H stretching mode indicates that OH does not participate in a hydrogen‐bonding network. |
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Keywords: | adsorption nickel oxygen vibrational spectroscopy water chemistry |
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