Oxidation of Cyclohexene in the Presence of Alkanes in a Barrier Discharge Plasma |
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| Authors: | S. V. Kudryashov A. Yu. Ryabov E. E. Sirotkina G. S. Shchegoleva |
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| Affiliation: | (1) Siberian Division, Russian Academy of Sciences, Institute of Petroleum Chemistry, Akademicheskii pr. 3, Tomsk, 634055, Russia |
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| Abstract: | ![]()
The oxidation of cyclohexene mixtures with hexane, octane, decane, and cyclohexane was studied in a dielectric-barrier discharge reactor. It was shown that a decrease in the partial pressure of cyclohexene in the mixture resulted in a significant increase in the yield of cyclohexene oxide to  75%, with the composition of oxidation products being the same as in the oxidation of individual compounds. A plausible mechanism of the reaction is proposed. |
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